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41.
Dr. Ashok Yadav Meghamala Sarkar Dr. Sappati Subrahmanyam Atul Chaudhary Prof. Dr. Evamarie Hey-Hawkins Prof. Dr. Ramamoorthy Boomishankar 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(19):4209-4213
The design of porous materials for the recognition of multiple hydrocarbons is highly desirable for the energy-efficient separation and recognition of chemical feedstock. Herein, three new iso-structural porous discrete metal–organic cages of formula {[Pd3(NiPr)3PO]4(R-AN)6} (R-AN=anilate linkers) for the selective recognition of substituted aromatic hydrocarbons are reported. The tetrahedral cages 1 , 2 , and 3 containing anilate, chloranilate, and bromanilate linkers exhibited selective encapsulation of mesitylene, o-xylene, and p-xylene, respectively, over other analogous aromatic hydrocarbons. These selective encapsulations were driven by the variations in the portal diameters present at each of these cages and their interactions with the hydrocarbon guests. These observations are supported by mass spectrometry, NMR studies, and theoretical binding-energy calculations. 相似文献
42.
43.
Suparna Chakraborty Manoj Kumar Mitra Mahua Ghosh Chaudhuri Biswanath Sa Satadal Das Rajib Dey 《Applied biochemistry and biotechnology》2012,168(7):2043-2056
Sol/gel-derived silica gel was prepared at room temperature from tetraethyl orthosilicate precursor. The extracts of Terminalia chebula (Haritoki) were entrapped into the porous silica gel. Fourier transform infrared analysis revealed the proper adsorption of herbal values in the nanopores of the silica gel. Porosity was estimated by transmission electron microscope studies. The release kinetics of the extract in both 0.1 N HCl, pH 1.2, and Phosphate-buffer saline (PBS), pH 7.2, were determined using UV–Vis spectroscopy. Different dissolution models were applied to release data in order to evaluate the release mechanisms and kinetics. Biphasic release patterns were found in every formulation for both the buffer systems. The kinetics followed a zero-order equation for first 4 h and a Higuchi expression in a subsequent timeline in the case of 0.1 N HCl. In the case of PBS, the formulations showed best linearity with a first-order equation followed by Higuchi’s model. The sustained release of the extract predominantly followed diffusion and super case II transport mechanism. The release value was always above the minimum inhibitory concentration. 相似文献
44.
45.
Dr. Mohd Nazish Dr. Mujahuddin M. Siddiqui Dr. Samir Kumar Sarkar Dr. Annika Münch Christina M. Legendre Dr. Regine Herbst-Irmer Prof. Dietmar Stalke Prof. Dr. Herbert W. Roesky 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(5):1744-1752
This work describes the synthesis and coordination behavior of a new mixed-donor ligand PhC(NtBu)2SiC6H4PPh2 ( 1 ) containing both silylene and phosphine donor sites. Ligand 1 was synthesized from a reaction of ortho-lithiated diphenylphosphinobenzene (LiC6H4PPh2) with chlorosilylene (PhC(NtBu)2SiCl). Treatment of 1 with Se and GeCl2 resulted in SiIV compounds 2 and 3 by selective oxidation of the silylene donor. This strong σ-donor ligand induces dissociation of CuCl and PhBCl2 leading to formation of ionic complexes 4 and 5 respectively. The reaction of 1 with ZnCl2 and AlCl3 resulted in the formation of chelate complexes 5 and 7 , respectively, while treatment with EtAlCl2 and GaCl3 forms monodentate complexes 8 and 9 . X-ray analysis of 4 showed that the copper is in the spiro center of the two five-membered rings. Moreover, the copper(I)chloride has not been oxidized but dissociates to Cu+ and [CuCl2]−. All the compounds are well characterized by mass spectrometry, elemental analysis, NMR spectroscopy, and single-crystal X-ray diffraction studies. 相似文献
46.
P. C. Deka H. Sarma Subir Sarkar T. D. Goswami B. K. Sarma 《Indian Journal of Physics》2009,83(7):1025-1030
With the growing understanding of the role of radon and its daughter products as major sources of radiation exposure, the
importance of large number of estimation of radon concentration in various parts of the country is realized. Inhalation of
radon, thoron and their decay products is the major source of the total radioactive dose received by the human population
from natural radiation. The indoor radon and thoron progeny levels in Nalbari area of Assam are studied by using the LR-115
(type II) Solid State Nuclear Track Detector in Plastic Twin Chamber dosimeter. Radon and thoron progeny levels in different
types of dwellings for one full calendar year are presented in this paper. For Assam Type (A.T.) houses, indoor radon progeny
concentrations vary from 0.17 to 0.64 mWL with an annual geometric mean of 0.27 mWL and that for Reinforced Cement Concrete
(R.C.C.) houses vary from 0.22 mWL to 0.60 mWL with the annual geometric mean of 0.37 mWL. The thoron progeny levels in A.T.
houses also vary from 0.01 to of 0.05 mWL with an annual geometric mean of 0.02 mWL and that for R.C.C. houses vary from 0.02
to 0.08 mWL with the annual geometric mean of 0.04 mWL.
相似文献
47.
One‐pot protocol for the synthesis of novel class of triazole linked 2‐sugar and 2‐aryl substituted benzimidazoles has been developed. The rapid and simple method involves copper (I) catalyzed simultaneous formation of benzimidazole and triazole rings at room temperature and in high yield. 相似文献
48.
A few cyclic and acyclic ketones were reduced in dichloro-methane, using reducing agents prepared from reusable montmorillonite clay supported phase transfer catalyst. A high percentage of axial attack (76–100%) by hydrides on substituted cyclohexanones observed, has been rationalised on the basis of a four center cyclic transition state for the clay absorbed ketone. 相似文献
49.
Andrew M. Bodratti Jiahui Wu Ruksana Jahan Biswajit Sarkar Marina Tsianou 《Journal of Dispersion Science and Technology》2013,34(12):1806-1815
Colloidal stabilization of nanoparticle dispersions is central to applications including coatings, mineral extraction, and dispersion of oil spills in oceanic environments, which often involves oil-mineral-aggregates (OMAs). We have an ongoing interest in the modulation of amphiphile micellization and adsorption behavior in aqueous colloidal dispersions in the presence of various additives. Here we evaluate the effect of added salts CaCl2, MgCl2, and NaCl on the micellization and adsorption behavior of the poly(ethylene oxide)-poly(propylene oxide)-poly(ethylene oxide) triblock copolymer Pluronic P105 (EO37PO56EO37). In 0.10 wt% silica nanoparticle (10.6 nm average diameter) dispersion, adsorbed block copolymer layer formation begins at a critical surface micelle concentration (csmc) of 0.02 wt%, well below the critical micellization concentration of Pluronic P105 in water. Dye solubilization experiments demonstrate an increase in the csmc upon addition of each salt. Each added salt reaches a level of maximum effectiveness in its ability to disfavor Pluronic P105 adsorption at the silica surface. These peak levels occur at concentrations of 0.005, 0.03, and 0.05 M for CaCl2, MgCl2, and NaCl, respectively, in the presence of 0.10 wt% silica nanoparticles. We explain these results in the context of an electrostatic displacer mechanism and discuss possible connections to OMA-dispersant formation. 相似文献
50.
Supratim Biswas Rajib Dey Siddhartha Mukherjee Pataki C. Banerjee 《Applied biochemistry and biotechnology》2013,170(7):1547-1559
Extraction of metals (Ni, Co) from chromite overburden of Sukinda mines of Orissa, India, with the culture filtrate of Aspergillus niger was studied. Results showed that the amounts of metals leached varied directly with reaction temperature and period of fermentation. The culture filtrate was analyzed for citric and oxalic acids, and contained only oxalic acid—the concentration of which increased with time. Although this acid played the major role in leaching of metals, other unidentified metabolites present in the culture filtrate influenced the dissolution of the metals significantly. Maximum recovery of metals from raw and roasted ore samples was achieved at 80 °C with the 21-day culture filtrate containing the highest amount of oxalic acid. Under identical experimental conditions, much higher amounts of the metals were leached from roasted ore. Microstructures of the ore particles were studied by scanning electron microscopy and transmission electron microscopy; the bonding behaviors of metal compounds were identified by Fourier transform infrared spectroscopy which showed that the metals were leached after chelation with oxalic acid. 相似文献